Citric Acid Monohydrate - Thailand

IUPAC Name

:   -

Cas Number

:   5949-29-1

HS Code

:   2918.14.00

Formula

:  

C6H8O7.H2O

Basic Info

Appearance Name

:   White Crystalline Powder

Common Names

:   Citric Acid Monohydrate

Packaging

: 25 Kg Bag

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Technical Document

About Citric Acid Monohydrate - Thailand

Citric acid, found naturally in citrus fruits, is a mild organic acid with the chemical formula C6H8O7. It plays a crucial role in the citric acid cycle, essential for the metabolism of aerobic organisms. The food and beverage industry heavily relies on citric acid, accounting for over 70% of the annual production exceeding a million tons worldwide. In this sector, it serves as an acidifier or antioxidant, enhancing and preserving the flavors and aromas of products like fruit juice, ice cream, and marmalades. Citric acid exists in two forms: monohydrate, which crystallizes in cold water, and anhydrous, which crystallizes in hot water. The anhydrous form can be obtained by heating citric acid monohydrate.

Manufacturing Process

Citric acid is manufactured through submerged fermentation utilizing fungi sourced from various carbohydrate-rich materials like molasses and starch-based media. During this process, calcium oxide is introduced for precipitation, leading to the formation of the slightly soluble tri-calcium citrate tetrahydrate. The resulting precipitate is separated through filtration and subjected to a washing step to eliminate impurities. Subsequent treatment with sulfuric acid transforms the precipitate into calcium sulfate, which is then filtered out. The citric acid liquid undergoes additional processing, including treatment with activated carbon and passage through both cation and anion exchangers. The final step involves concentrating the liquid in vacuum crystallizers at temperatures ranging from 20 to 25℃, resulting in the production of citric acid monohydrate.

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